Wow, I always thought this was a popular show. I'm surprised there is not much out there. Anyway, I've seen lists of about 27 (which is odd considering most are 26 including DragonFlyz...weird, maybe one is a special/pilot or a duplicate due to French translation issues).
1. The Sky's the Limit
2. On Wings of Song
3. Broken Stone
4. Getting the Story?
5. Lonely Heart
6. Dance, Jade, Dance
7. The Last Dance
8. Spread Your Wings
9. Love Lost, Love Found
10. Skyler vs Skyler
11. Blue Heaven
12. Time and Again
13. Statues
14. The Alliance
15. Forever Love
16. Sky Clone's Trap
17. Long Live Sky Clone!
18. Where's My Body?
19. Crises
20. The Moment of Truth
21. Heartbreak
22. Troublemakers
23. Dark Star
24. Slam Bang
25. The Imp's Trap
26. Treasure Cloud
27. The Purple Tide of Skyridium
I'm not 100% on the order as different sources are saying different things like Skylar vs Skylar I've seen listed as #2. The Sky's the Limit although the first episode I've also seen listed as #10..etc..etc but it should give you a good idea of what's out there (differences due to production and airing dates maybe?). Anyway, I think it is safe to say that no, not all are out on dvd yet.